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Electronic G2Electronic G3Electronic G4Electronic G5Photoresist & Lithography Solvents

Propylene Glycol Monomethyl Ether Acetate (PGMEA)

CH₃COOCH(CH₃)CH₂OCH₃ · CAS 108-65-6

Propylene Glycol Monomethyl Ether Acetate (PGMEA) is often shortlisted for arf immersion photoresist primary solvent (193i). In coating and lithography work, purity is only part of the decision: evaporation behaviour, water, acidity, residue and compatibility with the resist system should be reviewed together.

A common starting point

ArF immersion photoresist primary solvent (193i)

Molecular weight

132.16 g/mol

Boiling point

146 °C

Density

0.965 g/mL

High-purity optionsBatch documentationFlexible packaging review
Propylene Glycol Monomethyl Ether Acetate manufacturing, filling and industrial supply environment

Product identity

CAS number
108-65-6
Formula
CH₃COOCH(CH₃)CH₂OCH₃
Boiling point
146 °C
Density
0.965 g/mL

Product overview

A product route built around the application

Propylene Glycol Monomethyl Ether Acetate is considered for processes that need a consistent material, controlled critical impurities and a supply format that can move from qualification to routine use. The grade should be selected against the actual process—not a generic purity claim.

01

High-purity options

Compare listed grades and current product-specific limits.

02

Controlled attributes

Focus testing on the impurities and performance risks that matter.

03

Supply planning

Align sample, production pack, forecast and document route early.

Purification and controlled manufacturing route for Propylene Glycol Monomethyl Ether Acetate

Before you specify

A better enquiry starts with four answers

A higher grade is not automatically the better choice. The useful option fits the process, analytical method, packaging route and qualification plan without adding controls the application does not need.

01

Which resist, polymer or coating formulation is in use?

02

What evaporation, film-uniformity or edge-bead behaviour needs to be preserved?

03

Which water, acidity, peroxide and residue limits are already qualified?

04

What container, filtration and point-of-use connection are required?

Specification data

Compare the listed grade columns

This table is an indicative product overview for initial screening. Confirm the current controlled specification, test methods, reporting limits and available lot documentation before qualification or purchase.

ParameterTest methodUnitG4G5AR
Assay (GC)GC-FID%≥99.99≥99.999≥99.5
Water Content (KF)Karl Fischerppm≤30≤10≤2000
Total Metals (ICP-MS)ICP-MSppb ea.≤0.5<0.1
Acetic AcidGC-FIDppm≤20≤5≤50
1-Methoxy-2-Propanol (PGME)GC-FIDppm≤50≤20≤100
Propylene Glycol DiacetateGC-FIDppm≤30≤10
Acidity (as HAc)Titrationppm≤10≤5≤20
Residue on EvaporationGravimetricppm≤2≤0.5≤10
Color (APHA)ASTM D1209Hazen≤5≤5≤10
Peroxide (as H₂O₂)Iodometricppm≤1≤0.5≤5

Website values do not replace a signed sales specification. The agreed specification and lot-specific Certificate of Analysis govern supplied material.

Electronic grade context

Use the grade scale as a first comparison

SEMI C1 describes liquid-chemical grades and analytical procedures. A grade name helps organise a discussion; your process specification still decides which limits and methods are acceptable.

Electronic Grade Purity Comparison — SEMI C1 StandardG1 → G5
GradePurity (GC)Metals (ICP)ParticlesWater (KF)Process Node
G2
≥99.9%
≤10 ppb≤100/mL≤50 ppm≥180nm Mature Node
G3
≥99.99%
≤2 ppb≤20/mL≤20 ppm45–180nm
G4
≥99.999%
≤0.5 ppb≤10/mL≤10 ppm7–45nm
G5
≥99.9999%
<0.1 ppb≤5/mL≤5 ppm<7nm / EUV / Marangoni

All grades tested by ICP-MS (28 elements), in-line LPC (ISO Class 3 fill), and Karl Fischer titration. G5 = SEMI C1 Tier D. Full CoA per lot.  Request CoA template →

Where this product is used

Application routes for Propylene Glycol Monomethyl Ether Acetate

These examples help with discovery. They are not claims of universal suitability; material compatibility, process performance and the controlled specification still need review.

Propylene Glycol Monomethyl Ether Acetate industrial and analytical application environment

Semiconductor & electronics

  • ArF immersion photoresist primary solvent (193i)
  • EUV chemically-amplified resist (CAR) formulation
  • EUV metal oxide resist (MOR) formulation solvent
  • KrF / I-line positive photoresist primary solvent
  • Spin-on carbon (SOC) hard-mask dielectric solvent
  • Spin-on glass (SOG) intermetal dielectric solvent
  • Negative-tone developer (NTD) solvent in double patterning
  • OLED organic EL layer inkjet printing solvent
  • Polyimide (PI) precursor coating for HDI packaging

Laboratory & analytical

  • Polymer thin-film coating research
  • photocatalyst thin-film deposition
  • organic synthesis solvent

Industrial & other

  • Flat panel display (AMOLED/TFT-LCD) lithography
  • printed electronics R2R coating
  • gravure printing inks

Representative application cases

A practical evidence route for Propylene Glycol Monomethyl Ether Acetate

These are illustrative composite qualification scenarios, not named customer claims. Exact methods, limits and acceptance decisions belong to the customer’s controlled process.

CASE 01

European process qualification

A contamination-sensitive production team compares Propylene Glycol Monomethyl Ether Acetate (PGMEA) with its incumbent material using the agreed water, metals, organic-impurity, residue and particle controls.

Evidence route

Supplier CoA and specification data are evaluated alongside a representative process trial and incoming-control plan.

CASE 02

North American second-source review

A site qualifies Propylene Glycol Monomethyl Ether Acetate (PGMEA) for supply resilience without changing its approved process or dispensing route.

Evidence route

The review connects sample identity, production-pack compatibility, analytical comparison and documented change communication.

Purification, filtration, testing and clean filling for Propylene Glycol Monomethyl Ether Acetate

Manufacturing advantage

A controlled route from purification to final filling

The supply route for Propylene Glycol Monomethyl Ether Acetate connects incoming-material review, product-specific treatment, controlled transfer, testing, filling and lot documentation. Exact equipment and controls depend on the qualified product and grade.

01

Purification

Product-specific separation or treatment route.

02

Filtration

Compatible filtration and controlled transfer.

03

Testing

Release against the agreed specification.

04

Clean filling

Pack, closure and lot identification review.

Explore manufacturing →

Quality assurance & documentation

Evidence your quality team can review

Documents are matched to the supplied product, grade, lot and destination. The links below request the current controlled version; they are not static files with uncertain revision status.

Quality testing and controlled documentation for Propylene Glycol Monomethyl Ether Acetate

Packaging options

Choose the pack with the handling route in mind

Availability varies by grade and destination. Confirm container material, closure, headspace, connection, minimum order, dangerous-goods route and qualification-lot needs.

01

Qualification & laboratory packs

For evaluation, method work and lower-volume routine use.

1 L5 L
02

Drums & production packs

For regular production consumption and controlled dispensing.

20 L200 L
03

IBC & bulk routes

For higher-volume programmes after site, grade and logistics review.

IBC

Technical resources

Continue the technical review

Use application notes for context, then confirm current product documents before qualification.

Knowledge centre →

Start a product review

Need a reliable supply route for Propylene Glycol Monomethyl Ether Acetate?

Send the application, current specification, critical limits, pack, destination and forecast so the response can be technically useful.